Effect of Complexants on the Microstructure and Photocatalytic Activity of ZnO Thin Films[J]. Acta Scientiarum Naturalium Universitatis SunYatseni, 2010,49(5):77-82.
Effect of Complexants on the Microstructure and Photocatalytic Activity of ZnO Thin Films[J]. Acta Scientiarum Naturalium Universitatis SunYatseni, 2010,49(5):77-82.DOI:
a series of ZnO films were deposited on glass slide using sol-gel technique by altering the complexants (monoethanolamine
diethanolamine
triethanolamine). The phase composition
surface morphology
optical absorption property
surface chemical state
et al. was characterized by X-ray diffraction (XRD)
atomic force microscope (AFM)
UV-Vis absorption spectroscopy
X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL). The degradation of methylene blue impregnated on ZnO films were used to evaluate the photocatalytic activity of the three kinds of catalyst. The results showed that ZnO thin films prepared with monothanolmine showed excellent c-axis orientation
the main reason was considered as the shorter grain diffusion length. The higher phtocatalytic activity of ZnO films prepared with diethanolamine caused by relatively better optical absorption property and many oxygen defects.