1. 中山大学环境科学与工程学院,广,广州,510275
2.
3. 华南师范大学化学与环境学院∥广高校储能与动力电池产学研结合示范基地,广,广州,510006
纸质出版日期:2011,
网络出版日期:2011-11-25,
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黄艳玲, 何, 春, 等. 新型AgBr/GO复合催化剂的制备及其可见光催化还原CO2性能的初步研究[J]. 中山大学学报(自然科学版)(中英文), 2011,50(6):67-71.
Preparation and Photocatalytic Reduction of CO2 Using Novel AgBr/GO Nanocomposite Catalyst under Visible Light[J]. Acta Scientiarum Naturalium Universitatis SunYatseni, 2011,50(6):67-71.
采用液相合成法,在十三烷基三甲基溴化铵(CTAB)辅助下制备具有可见光效应的AgBr/GO复合材料,并考察其在可见光下催化还原CO
2
制备碳氢化合物的可行性及催化性能。XRD和TEM结果表明:AgBr纳米颗粒均匀地分散在GO载体表面,有利于光诱导下产生的电荷在AgBr与GO界面间的有效传递。可见光照射下,AgBr/GO复合催化剂还原CO
2
生成的甲烷、甲醇、CO和乙醇的产量分别是106.11、64.20、26.53和10.96 μmol·g
-1
明显高于AgBr的催化活性。AgBr/GO在重复使用5次后其光催化还原CO
2
的活性基本保持不变,因此AgBr/GO是一种高效的、光化学性质稳定的催化剂。
In this work
the AgBr/GO (graphite oxide) nanocomposite catalysts were prepared by the depositionprecipitation method in the presence of cetyltrimethylammonium bromide (CTAB)
and their photocatalytic activities were evaluated by the reduction yield in the presence of CO
2
and water under visible light (λ
>
420 nm). The results of X-ray diffraction (XRD) and scanning electron microscopy (SEM) showed that AgBr nanoparticles were well dispersed on the surface of GO supporter
which is beneficial to the transfer of photoexcited electrons from the conduction band of welldispersed AgBr to that of GO. The AgBr/GO nanocomposite had relatively high reduction yields under visiblelight irradiation for 5 h
with a methane yield of 106.11
methanol yield of 64.20
CO yield of 26.53
and ethanol yield of 10.96 μmol·g
-1
respectively. It was obvious that the catalytic activity of AgBr/GO was higher than that of AgBr. In addition
it was found that AgBr/GO photocatalyst was stable in the repeated uses under visible light. The total yields of the photocatalytic products and stability on AgBr/GO after the 5 repeated uses almost remained the same. Therefore
the AgBr/GO nanocomposite is an effective and stable visiblelightdriven photocatalyst for CO
2
photoreduction.
AgBr/GOCO2还原可见光
AgBr/GO nanocompositeCO2reductionvisible light
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