LI Gu, JIANG Juan, DONG Chaoxian. Preparation and Properties of CdS Particles in Zeolite and Its Modification for PE Composites[J]. Acta Scientiarum Naturalium Universitatis SunYatseni, 2012,51(4):56-60.
LI Gu, JIANG Juan, DONG Chaoxian. Preparation and Properties of CdS Particles in Zeolite and Its Modification for PE Composites[J]. Acta Scientiarum Naturalium Universitatis SunYatseni, 2012,51(4):56-60.DOI:
The zeolite loading nano-CdS particles (M-CdS) were prepared by situ-reaction between CdCl
2
absorbed in zeolite and Na
2
S solutions
and then were used to modify PE in order to get functional polymer composites. The optical properties and crystallization behavior were characterized by UV-Vis
PL and DSC analyses
respectively. The results showed that PE/M-CdS composites exhibited an obviously fluorescence emission in 540~550 nm
the emission shifted to longer wavelength and the intensity improve first
and then became weak with the increase of M-CdS contents. But the absorption strength between 280 nm and 325 nm in UV-Vis spectra of PE/M-CdS composites increased with the increment of M-CdS contents
at the same time the crystallization degree and melt enthalpy decrease. M-CdS showed the heterogeneous nucleation effect on PP/M-CdS composites
which displayed a higher crystallization temperature than PP.