中山大学光电材料与技术国家重点实验室∥ 物理科学与工程技术学院,广东,广州,510275
纸质出版日期:2013,
网络出版日期:2013-1-25,
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林国淙, 刘晖, 丁喜冬, 等. Ta间隙固溶体中的耦合弛豫[J]. 中山大学学报(自然科学版)(中英文), 2013,52(1):1-6.
LIN Guocong, LIU Hui, DING Xidong, et al. Coupling Relaxation in Interstitial Solid Solution of Tantalum[J]. Acta Scientiarum Naturalium Universitatis SunYatseni, 2013,52(1):1-6.
以广义Arrhenius方程对不同氧的原子个数百分比[
N
(O)]和不同氮的原子个数百分比[
N
(N)]的Ta间隙固溶体的内耗数据进行曲线拟合,并对结果进行了讨论。预设不同的
T
0
代替
T
C
得到标准差SD最小值时的自发有序温度
T
C
、指数前因子τ
0
和表观激活自由能
ΔG
对低弛豫元浓度的情况,由
T
0
-
ΔG
数据
T
0
是
T
C
附近的温度)线性拟合的截距得到激活焓
ΔH
由此计算熵的变化
ΔS
和参数τ′
0
。结果显示:①自发有序温度
T
C
与
N
(O)及
N
(N)基本上成正比的关系,显示随着
N
(O))或
N
(N)的增加,氧原子之间或氮原子之间的耦合增加,使自发有序温度
T
C
上升;②随着
N
(O)或
N
(N)的增加,组态熵的贡献
T
C
ΔS
增大,表观激活自由能
ΔG
下降;③参数τ′
0
基本不随
N
(O)变化,这一结果与“不同含氧量具有同一个激活焓
ΔH
”这一条件是自洽的,说明了在讨论的
N
(O)))范围弛豫元是相同的,是耦合的单个弛豫元;④
N
(N)小于1.0%时,弛豫元是耦合的单个弛豫元
N
(N)较大时,弛豫元发生变化,可能出现弱耦合的弛豫元对等,使
ΔS
增大。
In this paper
for the internal friction data of tantalum with oxygen or nitrogen
curve fitting was made by using generalized Arrhenius relation
and the results were discussed. To obtain a selfinduced ordering temperature
T
C
curve fitting was made with
T
C
replaced with
T
0
in generalized Arrhenius relation. Selfinduced ordering temperature
T
C
preexponential τ
0
and apparent activation free energy
ΔG
were calculated basing on the criteria of the minimum of the standard difference (SD) of curve fitting. For the situation with low concentration of relaxation unit
ΔH
is the interception of plot of
T
0
-
ΔG
where
T
0
is nearby the
T
C
. Then entropy change
ΔS
and factor τ′
0
can be calculated. The resultes are those as following: (1
T
C
is proportionate to the concentration of oxygen or nitrogen. This indicate that the the increase of oxygen or nitrogen in tantalum makes the coupling between oxygen or nitrogen increases
then makes
T
C
increase. (2)With the increase of oxygen or nitrogen in tantalum
T
C
ΔS
which is the contribution of combination entropy
increases
then makes the apparent activation free energy
ΔG
decrease. (3) Factor τ′
0
is almost a constant for tantalum with oxygen. The result is selfconsistent with the condition that there is a same activation enthalpy
ΔH
in it. These indicate that in the concentration range of oxygen in this paper
the relaxation unit is the same individual coupling unit. (4) For the situation of nitrogen concentration less than 1.0%
the relaxation unit is the same individual coupling unit. The relaxation unit changes when the concentration of nitrogen increases more. There may be some relaxation unit pairs with weak coupling in it
which make
ΔS
increase.
Arrhenius关系内耗耦合弛豫激活焓
arrhenius relationinternal frictioncoupling relaxationactivation enthalpy
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