TANG Jianzhao, RONG Teng, RONG Minzhi, et al. Preparation of Phenolic Foam Plastics Based on Fast Paralytic Oil of Biomass[J]. Acta Scientiarum Naturalium Universitatis SunYatseni, 2014,53(4):94-100.
TANG Jianzhao, RONG Teng, RONG Minzhi, et al. Preparation of Phenolic Foam Plastics Based on Fast Paralytic Oil of Biomass[J]. Acta Scientiarum Naturalium Universitatis SunYatseni, 2014,53(4):94-100.DOI:
Liquid bio-oil converted from renewable biomass is one of the important alternatives to petroleum in the future. In this work
wood creosote with more than 85% enrichment phenolic compounds was obtained by extraction purification of the wood tar. The main ingredients of the creosote include guaiacol
paracresol
etc.
which have good reactivity with formaldehyde. Then
w=50% of the wood creosote was used to substitute phenol for manufacturing wood creosote modified phenolic foam. The optimum conditions for preparing A-stage phenolic resin were determined by orthogonal test. It was found that the amount of NaOH catalyst was a key factor of preparing A-stage phenolic resin
and the curing of the foam plastics needed to use sulfuric acid as the catalyst. The foams-mechanical properties could be tailored by using different foaming processes. The amount of curing agent
foaming agents and foaming time and temperature exerted great influence on the foams properties. Under optimum conditions
a kind of foam with cell diameter of 200 μm
compressive strength of 1 003.8 kPa and modulus of 25.37 MPa was obtained
which satisfied the requirement of phenolic foam plastics of national standards.