WANG Huizhen, YANG Weiqing, YANG Haijun, et al. Synthesis and Fluorescence Properties of Quinolinone-Based Rare Earth Complexes[J]. Acta Scientiarum Naturalium Universitatis SunYatseni, 2015,54(4):93-98.
WANG Huizhen, YANG Weiqing, YANG Haijun, et al. Synthesis and Fluorescence Properties of Quinolinone-Based Rare Earth Complexes[J]. Acta Scientiarum Naturalium Universitatis SunYatseni, 2015,54(4):93-98.DOI:
Quinolinonebased rare earth complexes were synthesized from carboxylic acid derivatives of quinolinone (1). Their structures were characterized by FTIR
TG
MS analyses
and the complexes were determined to be [Ln(C
16
H
15
N
3
O
6
)X]·nH
2
O (Ln=Ce
Tb). The fluorescence properties of complexes and compound 1 were investigated. The result showed that the fluorescence intensity of cerium complex (2)〗 was 3.0 times as the compound 1. Meanwhile,the maximum fluorescence emission wavelength of complex 2 exhibited red shift (46 nm) compared to that of compound 1. The maximum fluorescence emission wavelength of terbium complex (3) exhibited red shift (46 nm) compared to that of compound 1. The peak pattern of the two lanthanide metal complexes was superior compared to that of compound 1 and metal ions. On the base of these results
the complexes have a good application prospect in optoelectronic field
and are significant to the technological development in biological detection and fluorescence imaging.