Synthesis of a 2D Zn （Ⅱ） coordination polymer and its fluorescence recognition of aristolochic acid A

WANG Kaimin; YANG Liangzhu; LI Lifeng; MA Yulu; FAN Baomin; SUN Weiqing

doi:10.13471/j.cnki.acta.snus.2022C017

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Synthesis of a 2D Zn （Ⅱ） coordination polymer and its fluorescence recognition of aristolochic acid A

Research articles | 更新时间：2023-11-01

- Synthesis of a 2D Zn （Ⅱ） coordination polymer and its fluorescence recognition of aristolochic acid A
- Acta Scientiarum Naturalium Universitatis Sunyatseni Vol. 62, Issue 3, Pages: 116-124(2023)
- 作者机构：
  
  1.云南民族大学化学与环境学院，云南昆明 650504
  2.昆明医科大学药学院 / 云南省天然药物药理重点实验室，云南昆明 650500
- 作者简介：
- 基金信息：
- DOI：10.13471/j.cnki.acta.snus.2022C017
  CLC： O 614.81⁺2
- Published：25 May 2023，
  
  Published Online：30 January 2023，
  
  Received：30 August 2022，
  
  Accepted：26 September 2022
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王凯民,杨良竹,李立凤等.二维Zn（Ⅱ）配位聚合物的制备及其对马兜铃酸A的荧光检测[J].中山大学学报(自然科学版),2023,62(03):116-124.

WANG Kaimin,YANG Liangzhu,LI Lifeng,et al.Synthesis of a 2D Zn （Ⅱ） coordination polymer and its fluorescence recognition of aristolochic acid A[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2023,62(03):116-124.
王凯民,杨良竹,李立凤等.二维Zn（Ⅱ）配位聚合物的制备及其对马兜铃酸A的荧光检测[J].中山大学学报(自然科学版),2023,62(03):116-124. DOI： 10.13471/j.cnki.acta.snus.2022C017.

WANG Kaimin,YANG Liangzhu,LI Lifeng,et al.Synthesis of a 2D Zn （Ⅱ） coordination polymer and its fluorescence recognition of aristolochic acid A[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2023,62(03):116-124. DOI： 10.13471/j.cnki.acta.snus.2022C017.

摘要

通过两性离子有机连接子4-羧基-1-（3-羧基苄基）吡啶-1-鎓氯化物，与含N桥连配体1，2-二（吡啶-4-基）乙烯、氢氧化钠一起在溶剂热条件下与Zn

自组装，构建了一例结构新颖具有二重穿插结构的二维配位聚合物

。采用X-射线单晶衍射、粉末衍射、热重分析、固体荧光等方法对配合物

的结构进行了表征，并考察了其在荧光传感材料领域的应用潜力。实验结果表明，配合物

可荧光猝灭选择性检测马兜铃酸A，且在5.0～35.0 μmol/L的低浓度范围，荧光猝灭率与马兜铃酸A浓度呈线性关系，检测限为0.022 μmol/L。其在检测马兜铃酸A时，响应时间仅需60 s，且在5次循环中能够保持结构的稳定。本研究制备的配合物

具有选择性、灵敏、高效、可回收荧光检测乙醇中马兜铃酸A的性能，可作为一种荧光传感器对低浓度的马兜铃酸A实现检测。

Abstract

A two-dimensional coordination polymer CP

with a double-intercalated structure was synthesized by zwitterionic organic ligand 4-carboxy-1-（3-carboxybenzyl）pyridine-1-onium chloride， 1，2-bis（pyridin-4-yl）ethene， NaOH and Zn

under solvothermal conditions. The structure of the CP

was characterized by the single-crystal X-ray structure， powder diffraction spectrum and thermal stability analysis. Its application potential in the field of fluorescence sensing materials was investigated by the solid fluorescence and liquid fluorescence analysis. Results show that CP

can identify aristolochic acid A by fluorescence quenching. In the low concentration range of 5.0～35.0 μmol/L， the quenching efficiency is linearly related to the concentration of aristolochic acid A， the detection limit was 0.022 μmol/L. The interaction time of CP

and aristolochic acid A is 60 s， and CP

can keep the structure stable in five cycles. The prepared CP

has good fluorescence properties， and has sensitive， rapid and recyclable fluorescence sensing performance for aristolochic acid A in ethanol， and it can be used as a fluorescence sensor to detect low concentration of aristolochic acid A.

关键词

配位聚合物两性离子配体马兜铃酸A荧光传感材料荧光检测

Keywords

coordination polymerzwitterionic ligandaristolochic acid Afluorescent sensing materialfluorescence detection

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Related Author

DONG Xueyan

MA Yulu

SUN Weiqing

FAN Ruifeng

BAI Xuling

ZHAO Xiong

DONG Yanqiu

DAI Zong

Related Institution

School of Pharmaceutical Sciences， Kunming Medical University / Yunnan Key Laboratory of Pharmacology for Natural Products

School of Chemistry， Sun Yat-sen University

School of Biomedical Engineering， Sun Yat-sen University

Qiannan Medical College for Nationalities， Duyun

College of Environment and Safety Engineering， Fuzhou University

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