Preparation and Photocatalytic Reduction of CO2 Using Novel AgBr/GO Nanocomposite Catalyst under Visible Light
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Preparation and Photocatalytic Reduction of CO2 Using Novel AgBr/GO Nanocomposite Catalyst under Visible Light
Acta Scientiarum Naturalium Universitatis SunYatseniVol. 50, Issue 6, Pages: 67-71(2011)
作者机构:
1. 中山大学环境科学与工程学院,广,广州,510275
2.
3. 华南师范大学化学与环境学院∥广高校储能与动力电池产学研结合示范基地,广,广州,510006
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Published:2011,
Published Online:25 November 2011,
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Preparation and Photocatalytic Reduction of CO2 Using Novel AgBr/GO Nanocomposite Catalyst under Visible Light. [J]. Acta Scientiarum Naturalium Universitatis SunYatseni 50(6):67-71(2011)
DOI:
Preparation and Photocatalytic Reduction of CO2 Using Novel AgBr/GO Nanocomposite Catalyst under Visible Light. [J]. Acta Scientiarum Naturalium Universitatis SunYatseni 50(6):67-71(2011)DOI:
Preparation and Photocatalytic Reduction of CO2 Using Novel AgBr/GO Nanocomposite Catalyst under Visible Light
the AgBr/GO (graphite oxide) nanocomposite catalysts were prepared by the depositionprecipitation method in the presence of cetyltrimethylammonium bromide (CTAB)
and their photocatalytic activities were evaluated by the reduction yield in the presence of CO
2
and water under visible light (λ
>
420 nm). The results of X-ray diffraction (XRD) and scanning electron microscopy (SEM) showed that AgBr nanoparticles were well dispersed on the surface of GO supporter
which is beneficial to the transfer of photoexcited electrons from the conduction band of welldispersed AgBr to that of GO. The AgBr/GO nanocomposite had relatively high reduction yields under visiblelight irradiation for 5 h
with a methane yield of 106.11
methanol yield of 64.20
CO yield of 26.53
and ethanol yield of 10.96 μmol·g
-1
respectively. It was obvious that the catalytic activity of AgBr/GO was higher than that of AgBr. In addition
it was found that AgBr/GO photocatalyst was stable in the repeated uses under visible light. The total yields of the photocatalytic products and stability on AgBr/GO after the 5 repeated uses almost remained the same. Therefore
the AgBr/GO nanocomposite is an effective and stable visiblelightdriven photocatalyst for CO