Synthesis of  p Phenylene Vinylene Polymer Photoluminescent MaterialIntermediate of 4-Butyloxyphenol by Phase Transfer Catalytic Reaction (I)

SHU Xuejun; LU Shenglin; XU Qianrui; SHI Weiwei; WU Yichao

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Synthesis of p Phenylene Vinylene Polymer Photoluminescent MaterialIntermediate of 4-Butyloxyphenol by Phase Transfer Catalytic Reaction (I)

更新时间：2023-12-11

- Synthesis of p Phenylene Vinylene Polymer Photoluminescent MaterialIntermediate of 4-Butyloxyphenol by Phase Transfer Catalytic Reaction (I)
- Acta Scientiarum Naturalium Universitatis SunYatseni Vol. 50, Issue 5, Pages: 79-82(2011)
- 作者机构：
  
  江西师范大学化学化工学院,江西,南昌,330022
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2011，
  
  Published Online：25 September 2011，
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SHU Xuejun, LU Shenglin, XU Qianrui, et al. Synthesis of p Phenylene Vinylene Polymer Photoluminescent MaterialIntermediate of 4-Butyloxyphenol by Phase Transfer Catalytic Reaction (I). [J]. Acta Scientiarum Naturalium Universitatis SunYatseni 50(5):79-82(2011)
DOI：

SHU Xuejun, LU Shenglin, XU Qianrui, et al. Synthesis of p Phenylene Vinylene Polymer Photoluminescent MaterialIntermediate of 4-Butyloxyphenol by Phase Transfer Catalytic Reaction (I). [J]. Acta Scientiarum Naturalium Universitatis SunYatseni 50(5):79-82(2011) DOI：

摘要

近几年来二烷氧基取代对苯乙炔聚合物(PPV)发光功能材料广泛应用于液晶彩电、电脑等家电和飞机彩色液晶显示屏中，该文研究了利用相转移催化反应在不同的催化剂反应条件下，合成二烷氧基取代对苯乙炔聚合物(PPV)发光功能材料的中间体4-丁氧基苯酚，在氢氧化钠存在下对苯二酚与溴代正丁烷60~65 ℃反应3 h条件下合成4-丁氧基苯酚，产品收率达90%以上。对不同的催化剂的使用和反应时间进行了条件优化，对产品4丁氧基苯酚的IR谱图、NMR谱图进行了确认和详细的分析。

Abstract

In recent years

Dialkoxyl substituted p phenylene vinylene polymer (PPV) photoluminescent function materials were widely applied in LED(LCD) TV

and computer

electrical equipments and aircraft color LED(LCD) displays. In this work

we used different catalysts to synthesize dialkoxyl substituted PPV photoluminescent function materials intermediate of 4-butyloxyphenol by phase transfer catalytic reaction. 4-Butyloxyphenol was synthesized using hydroquinone and butyl bromine in toluene solvent in the presence of sodium hydrate

by using different phase transfer catalyst. The product's yield was over 90% under the reaction temperature of 60~65 ℃ and the reaction time of 3.0 h. The different catalysts and reaction times were optimized and discussed. The structures of products were characterized by FTIR and NMR spectroscopy.

关键词

4-丁氧基苯酚相转移催化合成对苯二酚溴代正丁烷

Keywords

4-butyloxyphenolphase transfer catalysissynthesishydroquinonebutyl bromine

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