Coupling Relaxation in Interstitial Solid Solution of Tantalum
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Coupling Relaxation in Interstitial Solid Solution of Tantalum
Acta Scientiarum Naturalium Universitatis SunYatseniVol. 52, Issue 1, Pages: 1-6(2013)
作者机构:
中山大学光电材料与技术国家重点实验室∥ 物理科学与工程技术学院,广东,广州,510275
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Published:2013,
Published Online:25 January 2013,
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LIN Guocong, LIU Hui, DING Xidong, et al. Coupling Relaxation in Interstitial Solid Solution of Tantalum. [J]. Acta Scientiarum Naturalium Universitatis SunYatseni 52(1):1-6(2013)
DOI:
LIN Guocong, LIU Hui, DING Xidong, et al. Coupling Relaxation in Interstitial Solid Solution of Tantalum. [J]. Acta Scientiarum Naturalium Universitatis SunYatseni 52(1):1-6(2013)DOI:
Coupling Relaxation in Interstitial Solid Solution of Tantalum
for the internal friction data of tantalum with oxygen or nitrogen
curve fitting was made by using generalized Arrhenius relation
and the results were discussed. To obtain a selfinduced ordering temperature
T
C
curve fitting was made with
T
C
replaced with
T
0
in generalized Arrhenius relation. Selfinduced ordering temperature
T
C
preexponential τ
0
and apparent activation free energy
ΔG
were calculated basing on the criteria of the minimum of the standard difference (SD) of curve fitting. For the situation with low concentration of relaxation unit
ΔH
is the interception of plot of
T
0
-
ΔG
where
T
0
is nearby the
T
C
. Then entropy change
ΔS
and factor τ′
0
can be calculated. The resultes are those as following: (1
T
C
is proportionate to the concentration of oxygen or nitrogen. This indicate that the the increase of oxygen or nitrogen in tantalum makes the coupling between oxygen or nitrogen increases
then makes
T
C
increase. (2)With the increase of oxygen or nitrogen in tantalum
T
C
ΔS
which is the contribution of combination entropy
increases
then makes the apparent activation free energy
ΔG
decrease. (3) Factor τ′
0
is almost a constant for tantalum with oxygen. The result is selfconsistent with the condition that there is a same activation enthalpy
ΔH
in it. These indicate that in the concentration range of oxygen in this paper
the relaxation unit is the same individual coupling unit. (4) For the situation of nitrogen concentration less than 1.0%
the relaxation unit is the same individual coupling unit. The relaxation unit changes when the concentration of nitrogen increases more. There may be some relaxation unit pairs with weak coupling in it
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